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Study on the surface properties of colored talc filler (CTF) and mechanical performance of CTF/acrylonitrile-butadiene-styrene composite

机译:有色滑石填料的表面性能和CTF /丙烯腈-丁二烯-苯乙烯复合材料的力学性能研究

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摘要

Talc is a plate-like layered structure magnesium silicate mineral, in which the octahedral brucite layer is sandwiched between two tetrahedral silica sheets. Many reports have indicated an improvement in performance after a polymer matrix was reinforced with talc filler [1], [2], [3], [4] and [5]. However, it has been widely recognized that the filler nature of talc influences its reinforcement ability, depending on the surface activity, particle size, surface area, and surface functional groups [6] and [7]. Among these properties, surface activity affects the reinforcement ability of filler the most, because the chemical nature of a particle's surface determines filler–filler and filler-matrix interactions. These interactions in turn affect the filler's dispersion in the polymer matrix and thus the final performance of the composite. Therefore, a better understanding of a filler's surface properties is critical for determining the most effective polymer reinforcement fillers.However, to the best of our knowledge, the surface characterization of talc-derived fillers has been poorly reported and is poorly understood. In this work, a colored talc filler (CTF) was prepared, and its surface properties were subsequently studied and compared to those of talc filler (TF), using IGC and contact angle measurement. The mechanical properties of ABS composites filled with CTF and TF were investigated as well.
机译:滑石是板状层状结构的硅酸镁矿物,其中八面体水镁石层夹在两个四面体二氧化硅片之间。许多报道表明,用滑石填料[1],[2],[3],[4]和[5]增强聚合物基质后,性能得到改善。但是,人们已经广泛认识到,滑石粉的填料性质会影响其增强能力,具体取决于表面活性,粒径,表面积和表面官能团[6]和[7]。在这些特性中,表面活性对填料的增强能力的影响最大,因为颗粒表面的化学性质决定了填料之间的相互作用以及填料与基质之间的相互作用。这些相互作用继而影响填料在聚合物基质中的分散性,从而影响复合材料的最终性能。因此,更好地了解填料的表面性质对于确定最有效的聚合物增强填料至关重要。然而,据我们所知,滑石粉衍生的填料的表面特性很少得到报道,人们对此知之甚少。在这项工作中,制备了有色滑石填料(CTF),随后对其表面性能进行了研究,并使用IGC和接触角测量将其与滑石填料(TF)的表面性能进行了比较。还研究了填充有CTF和TF的ABS复合材料的力学性能。

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